资源类型

期刊论文 554

会议视频 16

会议信息 1

年份

2024 2

2023 39

2022 49

2021 43

2020 32

2019 30

2018 28

2017 23

2016 24

2015 20

2014 18

2013 17

2012 40

2011 32

2010 60

2009 22

2008 22

2007 17

2006 7

2005 8

展开 ︾

关键词

天然气 11

能源 8

勘探开发 7

普光气田 7

页岩气 5

天然气水合物 4

温室气体 4

中国 3

绿色化工 3

采油工程 3

三相界面 2

中国近海 2

低碳 2

光声 2

关键技术 2

分布特征 2

南海 2

可持续发展 2

增材制造 2

展开 ︾

检索范围：

排序： 展示方式：

Life-cycle analysis of energy use and greenhouse gas emissions of gas-to-liquid fuel pathway from steelmill off-gas in China by the LanzaTech process

Xunmin OU, Xu ZHANG, Qian ZHANG, Xiliang ZHANG

《能源前沿（英文）》 2013年 第7卷 第3期   页码 263-270 doi: 10.1007/s11708-013-0263-9

摘要： The LanzaTech process can convert carbon monoxide-containing gases produced by industries, such as steel manufacturing, into valuable fuel products. The life-cycle analysis (LCA) of energy use and greenhouse gas emissions from the LanzaTech process has been developed for a Chinese setting using the original Tsinghua China Automotive LCA model along with a customized module developed principally for the process. The LCA results demonstrate that LanzaTech gas-to-liquid (GTL) processing in China’s steel manufacturing is favorable in terms of life-cycle fossil energy and can reduce greenhouse gas emissions by approximately 50% compared with the conventional petroleum gasoline. The LanzaTech process, therefore, shows advantages in both energy-savings and a reduction in greenhouse gas emissions when compared with most bio-ethanol production pathways in China.

关键词： life-cycle analysis (LCA)     gas-to-liquid (GTL)     LanzaTech process    

HTML PDF 收藏

Simulation of interfacial Marangoni convection in gas-liquid mass transfer by lattice Boltzmann method

Shuyong CHEN, Xigang YUAN, Bo FU, Kuotsung YU

《化学科学与工程前沿（英文）》 2011年 第5卷 第4期   页码 448-454 doi: 10.1007/s11705-011-1142-8

摘要： Interfacial Marangoni convection has significant effect on gas-liquid and/or liquid-liquid mass transfer processes. In this paper, an approach based on lattice Boltzmann method is established and two perturbation models, fixed perturbation model and self-renewable interface model, are proposed for the simulation of interfacial Marangoni convection in gas-liquid mass transfer process. The simulation results show that the concentration contours are well consistent with the typical roll cell convection patterns obtained experimentally in previous studies.

关键词： interfacial Marangoni convection     lattice Boltzmann method     gas-liquid mass transfer    

HTML PDF 收藏

Trace analysis of off-flavor/odor compounds in water using liquid-liquid microextraction coupled withgas chromatography—positive chemical ionization-tandem mass spectrometry

Jian LU,Paul S. WILLS,P. CHRIS WILSON

《环境科学与工程前沿（英文）》 2016年 第10卷 第3期   页码 477-481 doi: 10.1007/s11783-015-0820-z

摘要： A rapid, inexpensive and laboratory friendly method was developed for analysis of off-flavor/odor compounds in fresh and salt water using gas chromatography with chemical ionization-tandem mass spectrometry. Off-flavor/odor compounds included geosmin, 2-methylisoborneol (MIB), 2-isobutyl-3-methyoxypyrazine (IBMP), and 2-isopropyl-3-methoxypyrazine (IPMP). Using this method, a single sample can be extracted within minutes using only 1 mL of organic solvent. The ion transitions for IPMP, IBMP, MIB, and geosmin were 153>121, 167>125, 152>95, and 165>109, respectively. The linearity of this method for analyzing MIB ranged from 4 to 200 ng·L , and from 0.8 to 200 ng·L for the other analytes. Method recoveries ranged from 97% to 111% and percent relative standard deviations ranged from 3% to 9%, indicating that the method is accurate, precise, and reliable.

关键词： off-flavor/odor compounds     liquid-liquid microextraction     gas chromatography-tandem mass spectrometry    

HTML PDF 收藏

Numerical simulation of three-dimensional gas/liquid two-phase flow in a proton exchange membrane fuel

ZHUGE Weilin, ZHANG Yangjun, LAO Xingsheng, CHEN Xiao, MING Pingwen

《能源前沿（英文）》 2007年 第1卷 第3期   页码 305-310 doi: 10.1007/s11708-007-0044-4

摘要： Investigation into the formation and transport of liquid water in proton exchange membrane fuel cells (PEMFCs) is the key to fuel cell water management. A three-dimensional gas/liquid two-phase flow and heat transfer model is developed based on the multiphase mixture theory. The reactant gas flow, diffusion, and chemical reaction as well as the liquid water transport and phase change process are modeled. Numerical simulations on liquid water distribution and its effects on the performance of a PEMFC are conducted. Results show that liquid water distributes mostly in the cathode, and predicted cell performance decreases quickly at high current density due to the obstruction of liquid water to oxygen diffusion. The simulation results agree well with experimental data.

关键词： diffusion     gas/liquid two-phase     management     exchange     transfer    

HTML PDF 收藏

Effect of counter current gas phase on liquid film

Shujuan LUO, Huaizhi LI, Weiyang FEI, Yundong WANG

《化学科学与工程前沿（英文）》 2009年 第3卷 第2期   页码 135-137 doi: 10.1007/s11705-009-0129-1

摘要： Liquid film flow is very important in many industrial applications. However, there are few reports about its characteristics on structured packings. Therefore, in this paper, liquid film phenomena were investigated experimentally to exploit new approaches for intensifying the performance of the structured packings. All experiments were performed at room temperature. Water and air were the working fluids. The effect of counter current gas phase on the liquid film was taken into consideration. A high speed camera, a non-intrusive measurement technique, was used. It is shown that both liquid and gas phases have strong effects on film characteristics. In the present work, liquid film width increased by 57% because of increasing liquid flow rate, while it decreased by 25% resulting from the counter current gas phase.

关键词： counter current     liquid film     two phases     structured packings    

HTML PDF 收藏

Detection of geosmin and 2-methylisoborneol by liquid-liquid extraction-gas chromatograph mass spectrum(LLE-GCMS) and solid phase extraction-gas chromatograph mass spectrum (SPE-GCMS)

MA Xiaoyan, CHEN Beibei, LI Qingsong, ZHANG Qiaoli, GU Guofen

《环境科学与工程前沿（英文）》 2007年 第1卷 第3期   页码 286-291 doi: 10.1007/s11783-007-0048-7

摘要： Two sample preparation methods were introduced and compared in this paper to establish a simple, quick and exact analysis of geosmin and 2-methylisoborneol. LC-18 column was employed in solid phase extraction (SPE), 1.0 mL of hexane was adopted in liquid-liquid extraction (LLE), and the extracts were analyzed by gas chromatograph mass spectrum (GCMS) in selected ion mode. Mean recoveries of SPE were low for 2-methylisoborneol (2-MIB) and geosmin (GSM) with values below 50%. For LLE, the recoveries were satisfyingly above 50% for 2-MIB and 80% for GSM. Detection limits of the LLE method were as low as 1.0 ng/L for GSM and 5.0 ng/L for 2-MIB. A year-long investigation on odor chemicals of drinking water in Shanghai demonstrated that in the summer, there was a serious odor problem induced by a high concentration of 2-MIB. The highest concentration of 152.82 ng/L appeared in July in raw water, while GSM flocculation was minimal with concentrations below odor threshold.

关键词： summer     flocculation     simple     Shanghai     spectrum    

HTML PDF 收藏

第14届国际气液和气液固反应器工程大会(International Conference on Gas-Liquid and Gas-Liquid-Solid Reactor Engineering)

会议日期： 2019年05月30日

会议地点： 中国/广西/桂林

主办单位： 中国科学院过程工程研究所，中国颗粒学会

Gas marbles: ultra-long-lasting and ultra-robust bubbles formed by particle stabilization

《化学科学与工程前沿（英文）》   页码 1681-1687 doi: 10.1007/s11705-022-2180-0

摘要： Bubbles and foams are ubiquitous in daily life and industrial processes. Studying their dynamic behaviors is of key importance for foam manufacturing processes in food packaging, cosmetics and pharmaceuticals. Bare bubbles are inherently fragile and transient; enhancing their robustness and shelf lives is an ongoing challenge. Their rupture can be attributed to liquid evaporation, thin film drainage and the nuclei of environmental dust. Inspired by particle-stabilized interfaces in Pickering emulsions, armored bubbles and liquid marble, bubbles are protected by an enclosed particle-entrapping liquid thin film, and the resultant soft object is termed gas marble. The gas marble exhibits mechanical strength orders of magnitude higher than that of soap bubbles when subjected to overpressure and underpressure, owing to the compact particle monolayer straddling the surface liquid film. By using a water-absorbent glycerol solution, the resulting gas marble can persist for 465 d in normal atmospheric settings. This particle-stabilizing approach not only has practical implications for foam manufacturing processes but also can inspire the new design and fabrication of functional biomaterials and biomedicines.

关键词： bubble     particles     interfaces     armored bubble     liquid marble     gas marble     Pickering emulsion    

HTML PDF 收藏

Gold modified cobalt-based Fischer-Tropsch catalysts for conversion of synthesis gas to liquid fuels

Alan J. McCue, Jura Aponaviciute, Richard P.K. Wells, James A. Anderson

《化学科学与工程前沿（英文）》 2013年 第7卷 第3期   页码 262-269 doi: 10.1007/s11705-013-1334-5

摘要： The addition of Au as a promoter/modifier for alumina supported Co catalyst has been studied by combined high temperature, high pressure Fourier transform infrared (FTIR) and on-line gas chromatography. The combination of these tools permitted the state of the active catalyst surface to be monitored while following the elution of reaction products during the first 5–7 h on stream of the catalyst. The catalysts under study were a 10%Co/Al O and a 2.5%Au/10%Co/Al O Samples were characterised before use using Raman and temperature programmed reduction (TPR). During the initial stages of reaction, hydrocarbons were built up on the surface of the catalyst as monitored by FTIR and the nature and amount of these species were assessed in terms of CH /CH ratio and the density of these alkyl fragments by employing absorption coefficients for the individual components. The nature and reducibility of the Co particles were modified by the presence of Au while the later also shifted the CO/H balance by acting as an effective water-gas shift catalyst during the early stages of reaction. This characteristic was lost during reaction as a consequence of redistribution of the two metallic phases.

关键词： gold modified catalyst     conversion of synthesis gas    

HTML PDF 收藏

Development of mobile miniature natural gas liquefiers

Yanxing ZHAO, Maoqiong GONG, Haocheng WANG, Hao GUO, Xueqiang DONG

《能源前沿（英文）》 2020年 第14卷 第4期   页码 667-682 doi: 10.1007/s11708-020-0695-y

摘要： With increasing consumption of natural gas (NG), small NG reservoirs, such as coalbed methane and oil field associated gas, have recently drawn significant attention. Owing to their special characteristics (e.g., scattered distribution and small output), small-scale NG liquefiers are highly required. Similarly, the mixed refrigerant cycle (MRC) is suitable for small-scale liquefaction systems due to its moderate complexity and power consumption. In consideration of the above, this paper reviews the development of mobile miniature NG liquefiers in Technical Institute of Physics and Chemistry (TIPC), China. To effectively liquefy the scattered NG and overcome the drawbacks of existing technologies, three main improvements, i.e., low-pressure MRC process driven by oil-lubricated screw compressor, compact cold box with the new designed heat exchangers, and standardized equipment manufacturing and integrated process technology have been made. The development pattern of “rapid cluster application and flexible liquefaction center” has been eventually proposed. The small-scale NG liquefier developed by TIPC has reached a minimum liquefaction power consumption of about 0.35 kW·h/Nm . It is suitable to exploit small remote gas reserves which can also be used in boil-off gas reliquefaction and distributed peak-shaving of pipe networks.

关键词： natural gas     mobile miniature liquefiers     mixed refrigerant cycle     vapor liquid equilibrium     heat transfer    

HTML PDF 收藏

Experimental study for the stratified to slug flow regime transition mechanism of gas-oil two-phase flow

LIU Yiping, YANG Weilin, WANG Jing

《能源前沿（英文）》 2008年 第2卷 第2期   页码 152-157 doi: 10.1007/s11708-008-0012-7

摘要： Theoretical relations that predict the transition from a stratified pattern to a slug pattern, including a one-dimensional wave model that contains less empiricism than the commonly used Taitel-Dukler model, and the ideal model for stratified flow for the gas-liquid flow in horizontal pipes are presented. Superficial velocities of each phase, as the onset of slugging occurs, were predicted, and theoretical analysis was conducted on the stratified to slug flow regime transition. The friction, existing between the fluid and pipe wall, and on the interface of two phases, was especially taken into account. A theoretical model was applied to an experiment about air-oil two-phase flow in a 50 mm horizontal pipe. The effect of pipe diameter on the transition was also studied. The results show that this approach gives a reasonable prediction over the whole range of flow rates, and better agreement has been achieved between predicted and measured critical parameters.

关键词： two-phase     Superficial     reasonable prediction     one-dimensional     gas-liquid    

HTML PDF 收藏

Chemical probe systems for assessing liquid–liquid mixing efficiencies of reactors

《化学科学与工程前沿（英文）》 2023年 第17卷 第10期   页码 1323-1335 doi: 10.1007/s11705-022-2275-7

摘要： Liquid–liquid mixing, including homogeneous and heterogeneous mixing, widely exists in the chemical industry. How to quantitatively characterize the mixing performance is important for reactor assessment and development. As a convenient and direct method for mixing characterization, the chemical probe method uses some special test reactions to characterize the mixing results. Here, the working principle and selection requirements of this method are introduced, and some common chemical probe systems for homogeneous and heterogeneous mixing processes are reviewed. The characteristics and applications of these systems are illustrated. Finally, the development of the new system is proposed.

关键词： mixing     chemical probe     liquid–liquid     heterogeneous    

HTML PDF 收藏

Microfluidic production of liposomes through liquid–liquid phase separation in ternary droplets

《化学科学与工程前沿（英文）》 2022年 第16卷 第6期   页码 1017-1022 doi: 10.1007/s11705-021-2118-y

摘要： Liposomes, the self-assembled phospholipid vesicles, have been extensively used in various fields such as artificial cells, drug delivery systems, biosensors and cosmetics. However, current microfluidic routes to liposomes mostly rely on water-in-oil-in-water double emulsion droplets as templates, and require complex fabrication of microfluidic devices, and tedious manipulation of multiphase fluids. Here we present a simple microfluidic approach to preparing monodisperse liposomes from oil-in-water droplets. For demonstration, we used butyl acetate-water-ethanol ternary mixtures as inner phase and an aqueous solution of surfactants as outer phase to make oil-in-water droplets, which can evolve into water-in-oil-in-water double emulsion droplets by liquid–liquid phase separation of ternary mixtures. Subsequently, the resultant water-in-oil-in-water droplets underwent a dewetting transition to form separated monodisperse liposomes and residual oil droplets, with the assistance of surfactants. The method is simple, does not require complex microfluidic devices and tedious manipulation, and provides a new platform for controllable preparation of liposomes.

关键词： microfluidics     liposomes     ternary droplets     phase separation    

HTML PDF 收藏

NICE’s Indirect Coal-to-Liquid Process for Producing Clean Transportation Fuels Using Fischer-Tropsch

Omar M. Basha,Li Weng,Zhuo-wu Men,Wayne Xu,Badie I. Morsi

《工程管理前沿（英文）》 2016年 第3卷 第4期   页码 362-376 doi: 10.15302/J-FEM-2016049

摘要： China is currently the world’s top coal consumer and the largest oil importer to sustain its rising economy and meet the mounting demand for transportation fuels. However, the increasing emissions due to the huge fossil fuels consumption, coupled with oil market instability, could derail China’s economic growth and jeopardize its national energy security. To face such a hurdle, China has been aggressively supporting low-carbon businesses opportunuties over the past decade, has recently announced several plans to cap coal utilization, and is currently the biggest investor in clean energy technologies. Coal-to-Liquid (CTL) is one of the most promising clean coal technologies, offering an ideal solution that can meet China’s energy demands and environmental expectations. It is widely known that the Shenhua Group has pioneered and is currently leading the commercialization of the Direct Coal Liquefaction (DCL) process in China. This paper highlights a part of the joint research effort undertaken by the National Institute of Clean-and-Low-Carbon Energy (NICE) and University of Pittsburgh in order to develop and commercialize the Indirect Coal Liquefaction (ICL) process. In this mission, NICE has built and operated an ICL plant including a large-scale (5.8-m ID and 30-m height) Slurry-Bubble-Column Reactor (SBCR) for Fischer-Tropsch synthesis using iron catalyst. The research, conducted at the University of Pittsburgh over the past few years, allowed building a user-friendly Simulator, based on a comprehensive SBCR model integrated with Aspen Plus and is validated using data from the NICE actual ICL plant. In this paper, the Simulator predictions of the performance of the NICE SBCR, operating with iron and cobalt catalysts under four different tail gas recycle strategies: (1) direct recycle; (2) using a Pressure Swing Adsorption (PSA) unit; (3) using a reformer; and (4) using a Chemical looping Combustion (CLC) process, are presented. It should be mentioned also that our joint research effort has laid the foundation for the design of a commercial-scale SBCR for producing one-million tons per annum of environmentally friendly and ultraclean (no sulfur, no nitrogen and virtually no aromatics) transportation fuels, which could greatly contribute to ensuring China’s national energy security while curbing its lingering emission problems.

关键词： Fischer-Tropsch synthesis     tail gas recycle     simulations     process design    

HTML PDF 收藏

标题 作者 时间 类型 操作

Life-cycle analysis of energy use and greenhouse gas emissions of gas-to-liquid fuel pathway from steelmill off-gas in China by the LanzaTech process

Xunmin OU, Xu ZHANG, Qian ZHANG, Xiliang ZHANG

期刊论文

Simulation of interfacial Marangoni convection in gas-liquid mass transfer by lattice Boltzmann method

Shuyong CHEN, Xigang YUAN, Bo FU, Kuotsung YU

期刊论文

Trace analysis of off-flavor/odor compounds in water using liquid-liquid microextraction coupled withgas chromatography—positive chemical ionization-tandem mass spectrometry

Jian LU,Paul S. WILLS,P. CHRIS WILSON

期刊论文

Numerical simulation of three-dimensional gas/liquid two-phase flow in a proton exchange membrane fuel

ZHUGE Weilin, ZHANG Yangjun, LAO Xingsheng, CHEN Xiao, MING Pingwen

期刊论文

Effect of counter current gas phase on liquid film

Shujuan LUO, Huaizhi LI, Weiyang FEI, Yundong WANG

期刊论文

Detection of geosmin and 2-methylisoborneol by liquid-liquid extraction-gas chromatograph mass spectrum(LLE-GCMS) and solid phase extraction-gas chromatograph mass spectrum (SPE-GCMS)

MA Xiaoyan, CHEN Beibei, LI Qingsong, ZHANG Qiaoli, GU Guofen

期刊论文

第14届国际气液和气液固反应器工程大会(International Conference on Gas-Liquid and Gas-Liquid-Solid Reactor Engineering)

2019年05月30日

会议信息

Gas marbles: ultra-long-lasting and ultra-robust bubbles formed by particle stabilization

期刊论文

Gold modified cobalt-based Fischer-Tropsch catalysts for conversion of synthesis gas to liquid fuels

Alan J. McCue, Jura Aponaviciute, Richard P.K. Wells, James A. Anderson

期刊论文

Development of mobile miniature natural gas liquefiers

Yanxing ZHAO, Maoqiong GONG, Haocheng WANG, Hao GUO, Xueqiang DONG

期刊论文

Experimental study for the stratified to slug flow regime transition mechanism of gas-oil two-phase flow

LIU Yiping, YANG Weilin, WANG Jing

期刊论文

张香平：基于离子液体的汽化离和转化过程（2019年5月25日）

2021年04月22日

会议视频

Chemical probe systems for assessing liquid–liquid mixing efficiencies of reactors

期刊论文

Microfluidic production of liposomes through liquid–liquid phase separation in ternary droplets

期刊论文

NICE’s Indirect Coal-to-Liquid Process for Producing Clean Transportation Fuels Using Fischer-Tropsch

Omar M. Basha,Li Weng,Zhuo-wu Men,Wayne Xu,Badie I. Morsi

期刊论文